The effect of heat treatment on the structure, microhardness and hardness of white cast iron
DOI:
https://doi.org/10.15407/mom2026.03.003Keywords:
white cast iron, heat treatment, microstructure, hardnessAbstract
This article presents the results of a study of the microstructure, microhardness, and hardness of unalloyed white cast iron after heat treatment with phase recrystallization using a normalization regime and accelerated cooling with compressor air at pressures of 0.2 and 0.6 MPa. The greatest increase in white cast iron hardness (from 74 to 79.5 HRA) occurs after heat treatment with compressor air cooling at a pressure of 0.6 MPa.
It has been shown that all heat treatment conditions lead to an increase in the microhardness of pearlite and cementite in the ledeburite structure, however, with different patterns for these structural components. The increase in pearlite microhardness occurs due to an increase in its dispersion and correlates with an increase in the cooling rate. No changes in the cementite microstructure after heat treatment are observed using conventional metallographic methods. Unlike pearlite, the change in cementite microhardness does not correlate with a change in the cooling rate. The increase in cementite microhardness occurs due to an increase in its minimum values before heat treatment. Significant heterogeneity in cementite microhardness was established, which is considerably higher than that of pearlite. Heat treatment with different cooling rates resulted in the formation of similar values for the maximum, minimum, and average microhardness of cementite.
It is suggested that the observed features of the change in the microhardness of cementite are associated with changes in its micro- and/or substructure, not detected by the applied research methods or its different chemical composition.
References
Guitar, M. A., Nayak, U. P., Britz, D., Mücklich F. (2020). The effect of thermal processing and chemical composition on secondary carbide precipitation and hardness in high-chromium cast irons. International Journal of Metalcasting. https://doi.org/10.1007/s40962-020-00407-4
Gundlach, R. B., Doane, D. V. (2014). Heat Treating of High-Alloy White Cast Cast Irons. ASM Handbook, V. 4D, Heat Treating of Irons and Steels, J. Dossett and G. E. Totten, editors, 527–535. https://doi.org/10.31399/asm.hb.v04d.a0005988
Chang Kyu Kim, Sunghak Lee, Jae-Young Jung. (2006). Effects of Heat Treatment on Wear Resistance and Fracture Toughness of Duo-Cast Materials Composed of High-Chromium White Cast Iron and Low-Chromium Steel. Metallurgical and materials transactions, V. 37A, March, 633–642. https://doi.org/10.1007/s11661-006-0035-9
Mbulelo Ngqase, Xiaowei Pan. (2020). Microstructural Investigation on Heat Treatment of Hypoeutectic High Chromium White Cast Irons. International Conference on Multifunctional Materials (ICMM-2019), Journal of Physics: Conference Series, 1495. https://doi.org/doi:10.1088/1742-6596/1495/1/012024.
Novikov, I. I. (1978). Teoriya termicheskoy obrabotki metallov [Theory of heat treatment of metals]. Metallurgiya. 392 p. [in Russian].
Hubertus Colpaert. (2017). Equilibrium Phases and Constituents in the Fe–C System. Metallogr Microstruct. Anal. 6, updated and translated by Andre´ Luiz V. da Costa e Silva. 443–457. https://doi.org/doi:10.1007/s13632-017-0383-4.
Mazur, A, Gasik, M. M., Mazur, V. I. (2005). Thermal analysis of eutectic reactions of white cast irons. Scandinavian Journal of Metallurgy, 34, 245–249. https://doi.org/10.1111/j.1600-0692.2005.00730.x
Bunin, K. P., Malinochka, Yа. N., Taran, Y. N. (1969). Osnovy metallografii chuguna [Fundamentals of cast iron metallography]. Metallurgiya. 416 p. [in Russian].
Li Hong, Wang Youming, Burdett, C. F. (1991). Hot deformation behaviour and ledeburite refinement mechanism for hypoeutectoid low alloy white cast irons. Materials Science and Technology, July V. 7. 660–664. https://doi.org/10.1179/mst.1991.7.7.660
Myronova, T. M. (2013). The influence of preliminary heat treatment on the plasticity of white cast irons. [Vplyv poperedn’oyi termichnoyi obrobky na plastychnist’ bilykh chavuniv.] Nauka ta prohres transportu. Visnyk Dnipropetrovsʹkoho natsionalʹnoho universytetu zaliznychnoho transportu № 6 (48). 88–98. https://doi.org/10.15802/stp2013/19679
Myronova, T, Ashkelianets, A, Chukhlib, V, Biba, N, Gubskii, S, Okun, A. (2021). Use of the dactyling effect to obtain a compositional structure in white iron during forming. Conf. Series: Materials Science and Engineering. 1164. https://doi.org/10.1088/1757-899X/1164/1/012005
Published
How to Cite
Issue
Section
License
Copyright (c) 2026 А.Ю. Борисенко, О.Д. Размахнін

This work is licensed under a Creative Commons Attribution 4.0 International License.