The structure and properties evolution of Al-Zn-Mg-Cu-Sc-Zr alloy after heat treatments

Authors

DOI:

https://doi.org/10.15407/mom2026.01.013

Keywords:

high-strength aluminum alloy, scandium, zirconium, MHD, mechanical properties

Abstract

This study is focused on the development and comprehensive analysis of the structural state and mechanical properties of a high-strength wrought aluminum alloy of the Al–Zn–Mg–Cu system, additionally alloyed with scandium (Sc) and zirconium (Zr). Alloys of this system are critically important materials for the aviation and defense industries due to their exceptional specific strength. The research addresses common challenges inherent to high-alloyed systems, such as susceptibility to hot cracking and dendritic segregation, by optimizing alloying element content and implementing innovative casting techniques.

The scientific novelty of this work lies in the investigation of the synergistic effect of Sc and Zr on the alloy's microstructure specifically in the as-cast state, an area less explored compared to wrought semi-finished products. It was established that the formation of Al3(Sc, Zr) intermetallic compounds ensures significant grain refinement, enhances anti-recrystallization stability, and contributes to additional strengthening through the precipitation of secondary coherent nanoparticles that remain stable during subsequent heat treatment.

The practical part of the research involved the production of a large-scale industrial ingot (150 mm in diameter) using a vacuum magnetohydrodynamic (MHD) installation and continuous casting into a short crystallizer with a thermal filling. This approach facilitated a uniform globular structure free of gas porosity, achieving a record-low hydrogen content (0.04–0.05 cm³/100 g). The evolution of the microstructure and phase transformations was studied using SEM, EDS, and DSC methods.

Mechanical testing results demonstrated that the applied casting technology ensures high isotropy of properties in both longitudinal and transverse directions. The alloy was found to exhibit high technological plasticity (elongation up to 53%) at temperatures of 300–400 °C, allowing for the optimization of further thermomechanical processing parameters, such as forging and rolling. The initial interphase melting temperature was determined to be 471–477 °C, serving as a fundamental parameter for establishing precise homogenization and solution treatment regimes for the experimental alloy.

References

Beletskiy, V. M., & Krivov, G. A. (2005). Aluminum alloys: Composition, properties, technology, application. Komintekh.

Starke, E. A., & Staley, J. T. (1996). Application of modern aluminum alloys to aircraft. Progress in Aerospace Sciences, 32(2-3), 131-172. https://doi.org/10.1016/0376-0421(95)00004-6

Williams, J. C., & Starke, E. A. (2003). Progress in structural materials for aerospace systems. Acta Materialia, 51(19), 5775-5799. https://doi.org/10.1016/j.actamat.2003.08.023

Dursun, T., & Soutis, C. (2014). Recent developments in advanced aircraft aluminium alloys. Materials & Design, 56, 862-871. https://doi.org/10.1016/j.matdes.2013.12.002

Georgantzia, E., Gkantou, M., & Kamaris, G. S. (2021). Aluminium alloys as structural material: A review of research. Engineering Structures, 227, 111372. https://doi.org/10.1016/j.engstruct.2020.111372

Yin, H., Wen, K., Li, Z., Li, X., Li, Y., Yan, L., Yan, H., Yu, M., Zhang, Y., & Xiong, B. (2023). Influence of Sc on microstructure and mechanical properties of Al-Zn-Mg-Cu alloys. Journal of Materials Research and Technology, 26, 6289-6302. https://doi.org/10.1016/j.jmrt.2023.08.138

Chen, Z., Mo, Y., & Nie, Z. (2013). Effect of Sc and Zr on microstructure and mechanical properties of Al-Zn-Mg-Cu alloys. Metallurgical and Materials Transactions A, 44, 3947-3958. https://doi.org/10.1007/s11661-013-1684-3

Tan, P., Sui, Y., Jin, H., Zhu, S., Jiang, Y., & Han, L. (2022). Effects of minor Sc and Zr on the microstructure and mechanical properties of Al-Zn-Mg-Cu alloys. Journal of Materials Research and Technology, 18, 2235-2244. https://doi.org/10.1016/j.jmrt.2022.03.168

Wen, K., Xiong, B., Ren, W., Tong, Y., Li, X., Li, Z., Zhang, Y., Li, Y., Yan, L., Yan, H., & Liu, H. (2020). Evolution of recrystallization and its impact on the mechanical properties of an Al-Zn-Mg-Cu-Sc-Zr alloy. Scripta Materialia, 186, 181-185. https://doi.org/10.1016/j.scriptamat.2020.05.045

Chen, K. H., Fang, H. C., Zhang, Z., Chen, X., & Liu, G. (2008). Effect of minor Sc and Zr on the microstructure and mechanical properties of Al-Zn-Mg-Cu alloy. Materials Science and Engineering: A, 498(1-2), 215-220. https://doi.org/10.1016/j.msea.2008.07.041

Lathabai, S., & Lloyd, P. G. (2002). The effect of scandium on the microstructure, mechanical properties and weldability of Al-Mg alloys. Acta Materialia, 50(17), 4271-4285. https://doi.org/10.1016/S1359-6454(02)00259-8

Costello, F. A., Robson, J. D., & Prangnell, P. B. (2002). Modelling the effect of Sc and Zr on the recrystallization of Al-Zn-Mg alloys. Materials Science Forum, 396-402, 757-762. https://doi.org/10.4028/www.scientific.net/MSF.396-402.757

Milman, Y. V., Sirko, A. I., Lotsko, D. V., Miracle, D. B., & Senkov, O. N. (2002). New Al-Mg-Li alloys with Sc and Zr. Materials Science Forum, 396-402, 1217-1222. https://doi.org/10.4028/www.scientific.net/MSF.396-402.1217

Costa, S., Puga, H., Barbosa, J., & Pinto, A. M. P. (2012). The effect of Sc and Zr additions on the microstructure and mechanical properties of Al-Mg-Sc-Zr alloys. Materials & Design, 42, 245-252. https://doi.org/10.1016/j.matdes.2012.06.019

Robson, J. D., & Prangnell, P. B. (2002). Modelling Al3Zr dispersion strengthening in Al-Zn-Mg alloys. Materials Science and Technology, 18(6), 607-614. https://doi.org/10.1179/026708302225003622

Mukhopadhyay, A. K., Kumar, A., Raveendra, S., & Samajdar, I. (2011). Effect of minor Sc additions on the microstructure and mechanical properties of Al-Zn-Mg-Cu-Zr alloys. Scripta Materialia, 64(5), 462-465. https://doi.org/10.1016/j.scriptamat.2010.10.038

Riddle, Y. W., & Sanders, T. H. (2000). A review of the metallurgy and applications of aluminum-scandium alloys. Materials Science Forum, 331-337, 799-804. https://doi.org/10.4028/www.scientific.net/MSF.331-337.799

Liu, J., Yao, P., Zhao, N., Shi, C., Li, H., Li, X., Xi, D., & Yang, S. (2016). Effect of minor Sc and Zr on the microstructure and mechanical properties of Al-Mg-Zn-Cu alloys. Journal of Alloys and Compounds, 657, 717-725. https://doi.org/10.1016/j.jallcom.2015.10.122

Senkova, S. V., Senkov, O. N., & Miracle, D. B. (2006). Microstructure and mechanical properties of a cast and wrought Al-Mg-Sc-Zr alloy. Metallurgical and Materials Transactions A, 37, 3361-3369. https://doi.org/10.1007/s11661-006-1051-5

Zou, L., Pan, Q. L., He, Y. B., Wang, C. Z., & Liang, W. J. (2007). Effect of minor Sc and Zr on microstructure and mechanical properties of Al-Zn-Mg-Cu alloy. Transactions of Nonferrous Metals Society of China, 17(2), 340-345. https://doi.org/10.1016/S1003-6326(07)60095-8

Deng, Y., Yin, Z. M., Zhao, K., Duan, J. Q., & He, Z. B. (2012). Effects of Sc and Zr on the microstructure and mechanical properties of Al-Zn-Mg-Cu alloys. Journal of Alloys and Compounds, 527, 106-111. https://doi.org/10.1016/j.jallcom.2012.03.108

Senkov, O. N., Bhat, R. B., Senkova, S. V., & Schloz, D. (2005). Microstructure and mechanical properties of a hot-rolled Al-Zn-Mg-Sc-Zr alloy. Metallurgical and Materials Transactions A, 36, 2115-2126. https://doi.org/10.1007/s11661-005-0332-8

Narivskiy, A., Shinsky, O., Shalevska, I., Kvasnitska, Y., Kaliuzhnyi, P., & Polyvoda, S. (2023). Modern technological processes of obtaining cast products and structures of responsible purpose from aluminum, ferrous carbon and heat-resistant alloys. In Structural materials: manufacture, properties, conditions of use (pp. 32-67). Kharkiv: Technology Center PC. https://doi.org/10.15587/978-617-7319-97-8.ch2

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Published

2026-03-31

How to Cite

Davydenko, O. A., Narivsky, A. V., Polyvoda, S. L., Bondarchuk, V. I., Molebnyi О. А., Tarasov, O. F., Tverdokhvalov, V. O., Sindalovsky, D., Kytranov, D. S., Semenko, A. Y., & Voron, M. M. (2026). The structure and properties evolution of Al-Zn-Mg-Cu-Sc-Zr alloy after heat treatments. Scientific Technical Journal ‘’Metal Science and Treatment of Metals’’, 32(1), 13–29. https://doi.org/10.15407/mom2026.01.013

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